SURFACE PLASMON RESONANCE OF GOLD/SILVER CORE/SHELL NANOROD WITH DIFFERENT THICKNESS OF SILVER SHELL

Authors

  • Do Thi Hue Thai Nguyen University of Education, Vietnam
  • Tran Thi Thu Huong Thai Nguyen University of Education, Vietnam
  • Tran Khac Khoi Thai Nguyen University of Education, Vietnam

DOI:

https://doi.org/10.51453/2354-1431/2021/455

Keywords:

Gold nanorods, silver NPs, surface plasmons, core /shell structure, AuR/Ag.

Abstract

This article shows the fabrication of AuR/Ag core/shell structural nanoparticles with the core of gold nanorods, the shells of silver nanoparticles according to the reduced method. This work involves two independent processes including the synthesis and optical properties survey of gold nanorods, then using the gold nanorods as the core particles for the next stage to form the core/shell structure AuR/Ag. Using UV-VIS absorption spectra to study the optical properties of the AuR/Ag core/shell structures and at the same time investigate the effect of the Ag+ concentration on the formation and optical properties of the AuR / Ag complex. The results showed that the optical properties of AuR / Ag strongly depend on the amount of the shell-forming precursor Ag+ ion. The greater the amount of Ag+, the thicker the silver crust, the plasmon resonance peaks of the fluid towards the shortwave, and the kinetic moment, the resonance peak at 353 nm with the contribution of electrons of the silver oscillating in the horizontal direction of the AuRs.

Downloads

Download data is not yet available.

References

[1] Chen, C.D., Cheng, S.F., Chau, L.K., Wang, C.R.C. (2007). Sensing capability of the localized surface plasmon resonance of gold nanorods, Biosens. Bioelectron, 926.

[2] Narayan, N., Meiyazhagan, A., & Vajtai, R. (2019). Metal Nanoparticles as Green Catalysts. Materials (Basel, Switzerland), 12(21), 3602. https://doi.org/10.3390/ma12213602.

[3] Gayda, G.Z., Demkiv, O.M., Stasyuk, N.Y., Serkiz, R.Y., Lootsik, M.D., Errachid, A., Gonchar, M.V., Nisnevitch, M. (2019). Metallic Nanoparticles Obtained via “Green” Synthesis as a Platform for Biosensor Construction, Applied Sciences, 9, 720.

[4] Abdal Dayem, A., Lee, S.B., Cho, S.G. (2018). The Impact of Metallic Nanoparticles on Stem Cell Proliferation and Differentiation, Nanomaterials, 8(10):761.

[5] Liu1, X., Shan, G., Yu, J., Yang, W., Ren, Z., Wang, Xx., Xie, X., Chen, H., Chen, X. (2017). Laser heating of metallic nanoparticles for photothermal ablation applications, AIP Advances, 7, 025308.

[6] Stefan Maier, A.M. (2007). Plasmonics: fundamentals and applications, Department of Physics, University of Bath, UK, 5, 67.

[7] Cristian, T., Daniela, T., Timea, S., Simion, A. (2014). Finite-Difference Time-Domain (FDTD) design of gold nanoparticle chains with specific surface plasmon resonance, Journal of molecular structure, 1072: 137-143.

[8] Shi, W., Sahoo, Y., Swihart, M.T. (2005). Gold Nano shells on Polystyrene Cores for Control of Surface Plasmon Resonance. Langmuir, 21(4): 1610-1617.

[9] Kim, M.H., Lu, X., Wiley, B., Lee, E.B., Xia, Y. (2008). Morphological Evolution of Single-Crystal Ag Nanospheres during the Galvanic Replacement Reaction with HAuCl4, The Journal of Physical Chemistry C, 112: 7872–7876.

[10] Skrabalak, S. E., Au, L., Li, X., Xia, Y. (2007). Facile synthesis of Ag nanocubes and Au nanocages, Nature Protocols, 2, 2182.

[11] Jana, N.R., Gearheart, L., and Murphy, C.J. (2001). Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods, The Journal of Physical Chemistry B, 105, 4065.

[12] Gole, A., and Murph, C.J. (2004). Seed-Mediated Synthesis of Gold Nanorods: Role of the Size and Nature of the Seed, Chemistry of Materials, 16, 3633.

[13] Liu, M., and Guyot-Sionnest, P. (2005). Mechanism of Silver(I)-Assisted Growth of Gold Nanorods and Bipyramids, The Journal of Physical Chemistry B, 109, 22192.

[14] Wiley, B.J., Xiong, Y., Li, Z.Y., Yin, Y., and Xia, Y. (2006). Right Bipyramids of Silver: A New Shape Derived from Single Twinned Seeds, Nano Letters, 6, 765.

[15] Olson, J., Dominguez-Medina, S., Hoggard, A., Wang, L.Y., Chang, W.S., Link, S. (2015). Optical characterization of single plasmonic nanoparticles. Chemical Society Reviews, 44: 40-57.

[16] Jia, H., Fang, C., Zhu, X.M., Ruan, Q., Wang, Y.X., Wang, J. (2015). Synthesis of absorption-dominant small gold nanorods and their plasmonic properties, Langmuir, 31, 7418.

[17] Ali, M.R.K., Rahman, M.A., Wu, Y., Han, H., Peng, X., Mackey, M.A., Wang, D., Shin, H.J., Chen, Z.G., Xiao, H. (2017). Efficacy, long-term toxicity, and mechanistic studies of gold nanorods photothermal therapy of cancer in xenograft mice, Proceedings of the National Academy of Sciences of the United States of America, 114, 3110.

[18] Zhang, J., and Zayats, A. (2013). Multiple Fano resonances in single-layer nonconcentric core-shell nanostructures”, Optics Express 21, 8426.

[19] Lu, L., Gwendolyn, B., Ionel, H., Dan, V.G. (2013). Core–shell gold/silver nanoparticles: Synthesis and optical properties”, Journal of Colloid and Interface Science, 392, 90.

[20] Lien, N.T.H., Ngan, L.T., Hue, D.T., Duong, V.T.T.D., Hoa, D.Q., Nhung, T.H. (2013). Preparation and characterization of silica–gold core–shell nanoparticles, Journal of Nanoparticle Research, 15, 2091, Vietnam.

[21] Ma, Y., Li, WW., Cho, E.C.., Li, Z., Yu, T., Zeng, J., Xie, Z., Xia, Y. (2010). Au@Ag Core−Shell Nanocubes with Finely Tuned and Well-Controlled Sizes, Shell Thicknesses, and Optical Properties, American Chemical Society Nano, 4, 6725.

[22] Gong, J., Zhou, F., Li, Z., Tang, Z. (2012). Synthesis of Au@Ag Core–Shell Nanocubes Containing Varying Shaped Cores and Their Localized Surface Plasmon Resonances, Langmuir, 28, 8959.

[23] Wu, L., Wang, Z., Zong, S., Huang, Z., Zhang, P., Cui, Y. (2012). A SERS-based immunoassay with highly increased sensitivity using gold/silver core-shell nanorods, Biosensors and Bioelectronics, 38, 94.

[24] Zong, S., Wang, Z., Yang, J., Wang, C., Xu, S., Cui, Y. (2012). A SERS and fluorescence dual mode cancer cell targeting probe based on silica coated Au@Ag core–shell nanorods”, Talanta, 15, 368.

[25] Ah, C. S., Hong, S. D., and Jang, D. J. (2001). Preparation of AucoreAgshell Nanorods and Characterization of Their Surface Plasmon Resonances, The Journal of Physical Chemistry B, 105, 7871.

[26] Liu, M., and Guyot-Sionnest, P. (2004). Synthesis and Optical Characterization of Au/Ag Core/Shell Nanorods, The Journal of Physical Chemistry B, 108, 5882.

[27] Hue, D.T., Duong, V.T.T., Nghia, N.T., Nhung, T.H., Lien, N.T.H. (2018). “Seeded Growth Synthesis Of Gold Nanorods For Photothermal Application”, Vietnam Journal of Science and Technology, 56: 148-157, Vietnam.

[28] Xiaolong, X., Yuanyuan, Z., Xiangdong, X., Shuaidong, H., Fei, C., Guozhang, Z., Xing-Jie, L. (2014). Seedless synthesis of high aspect ratio gold nanorods with high yield, Journal of Materials Chemistry A, 2, 3528.

[29] Ming-Zhang, W., Tian-Song, D., Zhang, Q., Zhiqun, Cc., Shiqi, L. (2021). Seed-Mediated Synthesis of Gold Nanorods at Low Concentrations of CTAB, ACS Omega 6, 13: 9188–9195.

[30] Murphy, C. J., Thompson, L.B., Chernak, D.J., Yang, Y.A., Sivapalan, S.T., Boulos, S.P., Huang, J., Alkilany, A.M., Sisco. P.N. (2011). Gold nanorod crystal growth: From seed-mediated synthesis to nanoscale sculpting. Current Opinion in Colloid & Interface Science. 16: 128–134.

[31] Yanan, M., Jun, Z., Weibo, Z., Zhenhong, J., Lucia, P., Pasquale, M. (2014). Localized Surface Plasmon Resonance and Surface Enhanced Raman Scattering Responses of Au@Ag Core–Shell Nanorods with Different Thickness of Ag Shell, Nanoscience and Nanotechnology, 14: 4245–4250.

[32] Linh, N., Mihir, D., Ober, M. F., Besteiro, L.V., Wang, Z.M., Nickel, B., Govorov, A. O., Liedl, L., Jungemann, A.H. (2020). Chiral Assembly of Gold–Silver Core–Shell Plasmonic Nanorods on DNA Origami with Strong Optical Activity, American Chemical Society Nano, 14: 7454–7461.

[33] Rodríguez, O. P., Núñez, P.D., Rubio, G. G., González, V. M., Rivera, A., Perlado, J. M., Junquera, E., & Martínez, A. G. (2020). Au@Ag Core–Shell Nanorods Support Plasmonic Fano Resonances”, Scientific Reports, 10, 5921.

[34] Dongxiang, L., Xiaofang, Z., Jie, Z., Chunxing, W., Taoran, Z., Chunfang, L., Meiwen, C. (2020). Shuttle-like core-shell gold nanorod@Ag-Au nanostructures: Shape control and electrocatalytic activity for formaldehyde oxidation, Applied Surface Science, 528, 1145.

Published

2021-08-17

How to Cite

Đỗ , T. H., Trần, T. T. H., & Trần, K. K. (2021). SURFACE PLASMON RESONANCE OF GOLD/SILVER CORE/SHELL NANOROD WITH DIFFERENT THICKNESS OF SILVER SHELL. SCIENTIFIC JOURNAL OF TAN TRAO UNIVERSITY, 7(21). https://doi.org/10.51453/2354-1431/2021/455

Issue

Section

Natural Science and Technology